Product ID:824 6266 CARTRIDGE TONER FOR COPIER I & II
MSDS Date:07/02/1997
FSC:6850
NIIN:01-389-9490
MSDS Number: BYTDD

IBM CORPORATION

OLD ORCHARD ROAD
ARMONK, NY 10504-1709
US

Emergency Phone: 800-426-4333/FAX 214-280-3903

Info Phone: 1-800-IBM-4333

Cage: 30874

IBM CORPORATION

ARMONK, NY 10504-1709 US

Telephone: 800-426-4333/FAX 214-280-3903

Cage: 30874

ACRYLIC COPOLYMER

CAS: 25608-33-7

Fraction By Weight: 60-65%

MALEATED RESIN

CAS: 8050-28-0

Fraction By Weight: 20-25%

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 5-10%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3; 9596

POLYVINYL STEARATE

Fraction By Weight: 1-5%

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL:EXPECTED TO BE LOW HAZ FOR
RECOMMENDED HNDLG.EYE:NO SPECIFIC HAZ KNOWN.MAY CAUSE TRANSIENT
IRRIT.SKIN:EXPECTED TO BE LOW HAZ FOR RECOMMENDED
HNDLG.INGEST:EXPECTED TO BE LOW INGEST HAZ.OVEREXPO T O CARBON
BLACK DUST MAY RESULT IN IRRITATION OF RESPIRATORY TRACT & BENIGN
DEPOSITION OF CARBON BLACK IN LUNG.
Explanation of Carcinogenicity:PER MSDS:CARC
CLASSIFICATION:ACGIH/NTP/OSHA:NONE.IARC:CARBON BLACK, 2B.
Effects of Overexposure:TRANSIENT EYE IRRITATION. IRRITATION OF
RESPIRATORY TRACT AND BENIGN DEPOSITION OF CARBON BLACK IN LUNG.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:SYMPTOMATIC MOVE TO FRESH AIR.TREAT
SYMPTOMATICALLY.SYMPTOMS PERSIST GET MED ATTN.EYE:ANY MATL THAT
CONTACTS EYE SHOULD BE WASHED OUT IMMED W/WATER.SYMPTOMS OCCUR GET
MED ATTN.SKIN:WASH W/SOAP/W ATER.SYMPTOMS OCCUR GET MED
ATTN.INGEST:DRINK 1-2 GLASSES OF WATER.SEEK MED ATTN.NEVER GIVE
ANYTHING BY MOUTH TO UNCONSC PERSON.

Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NP
Upper Limits:NP
Extinguishing Media:WATER SPRAY,CARBON DIOXIDE (CO2), DRY CHEMICAL.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:POWDERED MATERIAL MAY FORM EXPLOSIVE
DUST-AIR MIXTURES.COMBUSTIBLE SOLID.

Spill Release Procedures:DONT USE VACUUM CLEANER TO CLEAN UP SPILLS OF
POWDERED TONERS.THE VERY FINE PARTICLES CAN CAUSE FIRE OR
EXPLOSION.SWEEP MATERIAL ONTO PAPER & PLACE IN FIBER CARTON.AVOID
GENERATION OF DUST.CLEAN SURFA CE THOROUGHLY TO REMOVE RESIDUAL
CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID BREATH DUST.USE W/ADEQU
VENTI.POWDERED MATL MAY FORM EXPLO DUST-AIR MIXTURES.MIN DUST
GENERATION/ACCUMULATION.KEEP AWAY FRM IGN SOURCES.
Other Precautions:REF NFPA PAMPHLET#654:"PREVENTION OF FIRE/DUST EXPLO
IN CHEM/DYE/PHARMA/PLASTICS INDUSTRIES".KEEP FROM CONTACT
W/OXIDIZING MATLS.KEEP CNTNR CLSD.MATL HASNT BEEN TESTED FOR ENVIRO
EFFECTS.IN SPILL SITU ATION MATL MAY BE VISUALLY(SUPPLEMENTAL)

Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD VENTILATION(TYPICALLY 4-6RM VOL/HR)SHOULD BE
USED.VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS.
Protective Gloves:PROL/REP CONTACT,USE IMPERVIOUS GLOVES.
Eye Protection:GOOD INDUSTRIAL HYG PRAC TO MIN CONTACT.
Other Protective Equipment:WASHING FACILITIES, EYE BATH, SAFETY SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
OTHER PRECAUT:HOWEVER ITS NOT EXPECTED TO CAUSE ANY ADVERSE ENVIRO
EFFECTS.

HCC:N1
Boiling Pt:B.P. Text:NP
Melt/Freeze Pt:M.P/F.P Text:167F,75C
Decomp Temp:Decomp Text:NP
Vapor Pres:NEGLIGIBLE
Vapor Density:NA
Spec Gravity:0.9
pH:NA
Viscosity:NP
Evaporation Rate & Reference:NP
Solubility in Water:NELGIGIBLE
Appearance and Odor:SOLID (POWDER), BLACK COLOR, SLIGHT ODOR
Percent Volatiles by Volume:NA
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:HAZ COMBUSTION PRODUCTS:CARBON
DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, OXIDES OF SULFUR.

Waste Disposal Methods:CAN BE INCINERATED WHEN IN COMPLIANCE W/LOC
REGS.DISCHARGE/TREAT/DISPO SUBJ TO NAT/STATE/LOC LAWS.CHEM SUBJ TO
REPORT REQMTS SEC 313 TITLE III SARA/40CFR3723:NONE.

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particular situation.